Orthorhombic modification of bis[4-(3-pyridylmethylideneamino)phenyl]methane
نویسندگان
چکیده
The title compound, C(25)H(20)N(4), is a disubstituted methane derivative having two pyridyl-methyl-ene-amino-phenyl arms, one of which is essentially rigid as all atoms lie on a plane (r.m.s. deviation = 0.074 Å), whereas the other is twisted [dihedral angle between the phenyl-ene and pyridyl rings = 51.1 (4)°]. The angle at the methyl-ene C atom is 113.2 (2)°.
منابع مشابه
Bis([μ-bis(diphenylarsino)methane-1:2κ2 As:As’]nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-{tris[4-(methylsulfanyl)phenyl]arsine-3κAs}-triangulo-triruthenium(0)) dichloromethane monosolvate
The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)As(2))(C(21)H(21)AsS(3))(CO)(9)]·CH(2)Cl(2), consists of one triangulo-triruthenium complex mol-ecule and one half of a dichloro-methane mol-ecule which lies across a crystallographic inversion center, leading to the disorder of this mol-ecule over two positions of equal occupancy. The bis-(diphenyl-arsino)metha...
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The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(21)H(21)AsS(3))(C(25)H(22)P(2))(CO)(9)]·CH(2)Cl(2), consists of one triangulo-triruthenium complex mol-ecule and one half of a dichloro-methane mol-ecule which lies across a crystallographic inversion center, leading to the disorder of this mol-ecule over two positions of equal occupancy. The bis-(diphenyl-phosphino)met...
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متن کاملDi-μ-chlorido-bis{bis[3,5-dimethylpyrazol-1-yl-κN 2)methane]iron(II)} bis[tetrachloridoferrate(III)]
In the title complex, [Fe(2)Cl(2)(C(11)H(16)N(4))(4)][FeCl(4)](2), the asymmetric unit is composed of one and a half units of [Fe(bdmpm)(2)Cl](2)(FeCl(4))(2)(bdmpm = bis(bis(3,5-dimethyl-pyrazol-1-yl)methane). The three independent Fe(II) atom have a distorted octa-hedral coordination geometry comprising two bridging chloride anions and four N atoms from two bis-(3,5-dimethyl-pyrazol-1-yl)metha...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010